Bryan Research & Engineering
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Technical paper

Design and Optimization of Integrated Amine Sweetening, Claus Sulfur and Tail Gas Cleanup Units by Computer Simulation

  • John C. Polasek - Bryan Research & Engineering, LLC
  • Jerry A. Bullin - Texas A&M University / Bryan Research & Engineering, LLC
  • 1990
  • Gas Processors Association

Integrated gas sweetening, sulfur and tail gas cleanup units (TGCU) were analyzed by a process simulation program, called TSWEET, to determine the sensitivity of the operating conditions and parameters on the performance of the system. The parameters investigated included the H2S/CO2 ratio in the acid gas from the main absorber, the hydrocarbon content of the acid gas, the reaction model for H2 and CO in the furnace, the formation and reaction of COS as well as CS2 and the CO2 slippage in the TGCU absorber. For the assortment of cases considered, the results showed that while some parts of the system were not overly sensitive to many of the operating conditions others were quite sensitive. Due to the complexity of the integrated system, a parameteric analysis is necessary to fully optimize the system.

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Integrated gas sweetening, sulfur and tail gas cleanup units (TGCU) were analyzed by a process simulation program, called TSWEET, to determine the sensitivity of the operating conditions and parameters on the performance of the system. The parameters investigated included the H2S/CO2 ratio in the acid gas from the main absorber, the hydrocarbon content of the acid gas, the reaction model for H2 and CO in the furnace, the formation and reaction of COS as well as CS2 and the CO2 slippage in the TGCU absorber. For the assortment of cases considered, the results showed that while some parts of the system were not overly sensitive to many of the operating conditions others were quite sensitive. Due to the complexity of the integrated system, a parameteric analysis is necessary to fully optimize the system.